Allen: Unlock when you collect more stars than your opponent before the time runs out on the D.gray.man first mission

Don patch: Avoid being hit for at least 2 minutes in the 2 mission of bo-bobo

Gohan: Clear the stage in 30 seconds or less in the second mission of DBZ

Gon: get the most points to win on the first mission in Hunter x Hunter

Kakashi: KO at least 2 opponents with a special attack in mission 2 of Naruto

Kazuki: KO all the opponents in the first and only mission in Busou Renkin

Kenshin: KO with at least 3X attacks on the first mission of Rurouni Kenshin

Killua: Get 4 points more than your opponent in the first mission in Hunter x Hunter

Kyubii naruto (Demon fox Naruto): unlock Jiraya and evolve him then get the path to Kyubii Naruto

Nami: collect 30 coins In one piece on the third mission

Piccolo: Collect All 7 dragon balls on the third mission of DBZ

Sakura: Finish mission 3 of Naruto with full health

Sanji: Collect more stars than your opponent before the time runs out on the second One Piece mission

Sasuke: KO 2 times with an attribute better than the opponent's

Seiya: Get the most points to win on the first mission os Saint Seiya

Train: Collect more stars than your opponent before the time runs out in the first mission in Black Cat

Vegeta: Never use special attacks in Mission two of DBZ

Zoro: Get the most points on the first mission on the One Piece planet

19XX Wasteland (Hokuto No Ken): Toki: Collect all stars in 30 seconds during Hokuto No Ken mission 3

Celestial Tower (Hunter X Hunter): Biscuit Kreuger: Complete Hunter X Hunter mission 4 in under 4 minutes

Cityscape: Natsuhiko Taki (Eyeshield 21): Ring out 1 opponent during Eyeshield 21 mission 4

Dark Religion Headquarters (D.Gray-Man): River Wenham: Collect 3 or more stars during D.Gray-Man mission 1

Dark Tournament Stadium (Yu Yu Hakusho): Kazuma Kuwabara: Get a KO with a Support attack during Yu Yu Hakusho mission 1

Davey Back Fight (One Piece): Roronoa Zoro: Complete One Piece mission 1

Dio's Mansion (Jojo's Bizarre Adventure): Dio Brando: Get 2 KOs with Support attacks during Planet X: Boss Tower mission 7

Final Battleground: River Wenham: Collect at least 3 stars during D.Gray-Man mission 1

Flute Stage (Pyuu To Fuku! Jaguar): Jirou Hame: Complete Pyuu To Fuku! Jaguar mission 1

Football Stadium (Eyeshield 21): Haruto Sakuraba: Ring out 2 opponents during Eyeshield 21 mission 4

Future Edo (Gintama): Taizo Hasegawa: Complete Gintama mission 3

Gates of Babylon (Shaman King): Chocolove McDaniel: Complete Shaman King mission 2

Hanage Empire (Bobobo-bo Bo-bobo): Dengakuman: Complete Bobobo-bo Bo-bobo mission 3

JUMP: Dr. Masahirito: Finish the J-Adventure mode. You need his evolution path from Obotchaman (Finish Boss Tower mission 3 without specials)

Kamiya Dojo (Rurouni Kenshin): Yahiko Myojin: Complete Rurouni Kenshin mission 1

Konoha Village (Naruto): Jiraiya: Finish in under 20 seconds on Planet U mission 1

L.X.E. Headquarters (Busou Renkin): Tokiko Tsumura: Get 2 KOs using attacks of a stronger nature than the targets in the Busou Renkin mission

Manga Battle: Hao (Shaman King): Get at least 3 points in Shaman King mission 1

Manga Page: Bat (Hokuto No Ken): Complete Hokuto No Ken mission 2

Millenium Puzzle (Yu-Gi-Oh!): Hiroto Honda: Don't get KO'd by Ring Out in Yu-Gi-Oh! mission 2

Norimaki Household (Dr. Slump): Midori Yamabuki: KO Arale within 40 seconds on Dr. Slump mission 2

Outer Space: Crystal Boy: Complete the Space Adventure Cobra mission without being KO'd

Outside Swada Hospital (Katekyo Hitman Reborn!): Lambo: Don't use Special Attacks in Katekyo Hitman Reborn! mission 1

Planet Namek (Dragon Ball): Piccolo: Collect all 7 Dragon Balls within 30 seconds in Dragon Ball mission 3

Police Station (Kochi Kame): Matoi Giboshi: Don't get KO'd by Ring Out in Boss Tower mission 1

Safe House (Black Cat): Eve: Collect all stars within 40 seconds in Black Cat mission 1

Sanctuary (Saint Seiya): Shun: Break all walls within 1 minute in Saint Seiya mission 3

School Festival (Ichigo 100%): Satsuki Kitaooji: Collect at least 3 stars in Ichigo 100% mission 1

School Grounds (Jigoku Sensei Nube): Yukime: Get 5 more points than your opponent in the Jigoku Sensei Nube mission

Shohoku High Gymnasium (Slam Dunk): Haruko Akagi: Complete Slam Dunk mission 2

Soul Society (Bleach): Kaname Tousen: Get a KO with a Special Attack during Bleach mission 5

Tennis Court (Prince of Tennis): Oishi/Eiji: Get 4 KOs using Support Characters in Prince of Tennis mission 3

Tournament Mountain (Kinnikuman): Asuraman: Don't get hit with a Special Attack in Planet U mission 3

Trial By Fire (Sakigake!! Otokojuku): Hien: Get 2 KOs using Special Attacks in Sakigake!! Otokojuku mission 1

World of Shikigami (Death Note): Mello: Don't use Special Attacks in Death Note mission 2